Studi Pengaruh Konsentrasi Katalis ZnO untuk Degradasi Limbah Palm Oil Mill Effluent (POME) Menggunakan Teknologi Fotokatalitik
DOI:
https://doi.org/10.55893/jt.vol22no2.549Keywords:
POME, photocatalytic, COD, radical, ZnOAbstract
Indonesia is among the world’s largest palm oil market countries leading to significant growth in the domestic palm oil industry. However, the increase in palm oil trading has also led to a rise in the production of waste known as Palm Oil Mill Effluent (POME). Currently, the majority of factories use open ponds for POME processing, but this method is considered ineffective for treating POME. To address this issue, researchers are exploring photocatalytic technology, which utilizes light energy (UV, visible, sunlight) to produce radical compounds that act as oxidizing agents for POME degradation. In this study, ZnO was employed as a catalyst. The XRD and UV-vis DRS characterizations confirmed that ZnO had a hexagonal wurtzite crystal structure with a band gap energy of 3,22 eV. The photocatalytic activity test results revealed that using 0.5 g/L ZnO catalyst proved to be efficient in degrading organic content in POME. The percentage of chemical oxygen demand (COD) degradation reached 22.85%, color degradation reached 48.53% and the reaction rate kinetics constant of COD degradation was at 2.6´10-3 min-1.
References
Abdullah, H., Khan, M. M. R., Ong, H. R., & Yaakob, Z. (2017). Modified TiO2 photocatalyst for CO2 photocatalytic reduction: An overview. Journal of CO2 Utilization, 22(March), 15–32. https://doi.org/10.1016/j.jcou.2017.08.004
Ameta, R., Solanki, M. S., Benjamin, S., & Ameta, S. C. (2018). Photocatalysis. Dalam Advanced Oxidation Processes for Wastewater Treatment: Emerging Green Chemical Technology (hlm. 135–175). https://doi.org/10.1016/B978-0-12-810499-6.00006-1
Badrun, Y., Retnawati, S. F., Fauzi, M. R., Harahap, I., & Anggraini, D. A. (2019). Analisis pencemaran sungai Rokan akibat kegiatan pabrik kelapa sawit. 2018, 24–36.
Charles, A., & Cheng, C. K. (2019). Photocatalytic treatment of palm oil mill effluent by visible light-active calcium ferrite: Effects of catalyst preparation technique. Journal of Environmental Management, 234, 404–411. https://doi.org/10.1016/j.jenvman.2019.01.024
Charles, A., Khan, M. R., Ng, K. H., Wu, T. Y., Lim, J. W., Wongsakulphasatch, S., Witoon, T., & Cheng, C. K. (2019). Facile synthesis of CaFe2O4 for visible light driven treatment of polluting palm oil mill effluent: Photokinetic and scavenging study. Science of the Total Environment, 661, 522–530. https://doi.org/10.1016/j.scitotenv.2019.01.195
Cheng, C. K., Deraman, M. R., Ng, K. H., & Khan, M. R. (2016). Preparation of titania doped argentum photocatalyst and its photoactivity towards palm oil mill effluent degradation. Journal of Cleaner Production, 112, 1128–1135. https://doi.org/10.1016/j.jclepro.2015.06.104
Cheng, C. K., Rizauddin Derahman, M., & Khan, M. R. (2015). Evaluation of the photocatalytic degradation of pre-treated palm oil mill effluent (POME) over Pt-loaded titania. Journal of Environmental Chemical Engineering, 3(1), 261–270. https://doi.org/10.1016/j.jece.2014.10.016
Cheng, Y. W., Chang, Y. S., Ng, K. H., Wu, T. Y., & Cheng, C. K. (2017). Photocatalytic restoration of liquid effluent from oil palm agroindustry in Malaysia using tungsten oxides catalyst. Journal of Cleaner Production, 162, 205–219. https://doi.org/10.1016/j.jclepro.2017.06.023
Hodzic, A., Madronich, S., Kasibhatla, P. S., Tyndall, G., Aumont, B., Jimenez, J. L., Lee-Taylor, J., & Orlando, J. (2015). Organic photolysis reactions in tropospheric aerosols Organic photolysis reactions in tropospheric aerosols: effect on secondary organic aerosol formation and lifetime Organic photolysis reactions in tropospheric aerosols Organic photolysis reactions in tropospheric aerosols. Atmos. Chem. Phys. Discuss, 15, 8113–8149. https://doi.org/10.5194/acpd-15-8113-2015
Karthikeyan, C., Arunachalam, P., Ramachandran, K., Al-Mayouf, A. M., & Karuppuchamy, S. (2020). Recent advances in semiconductor metal oxides with enhanced methods for solar photocatalytic applications. Dalam Journal of Alloys and Compounds (Vol. 828). Elsevier Ltd. https://doi.org/10.1016/j.jallcom.2020.154281
Lam, S. M., Wong, K. A., & Sin, J. C. (2018). Fabrication of Flower-like ZnO Micro/Nanostructures for Photodegradation of Pre-treated Palm Oil Mill Effluent. IOP Conference Series: Earth and Environmental Science, 112(1). https://doi.org/10.1088/1755-1315/112/1/012003
León, D. E., Zúñiga-Benítez, H., Peñuela, G. A., & Mansilla, H. D. (2017). Photocatalytic Removal of the Antibiotic Cefotaxime on TiO2 and ZnO Suspensions Under Simulated Sunlight Radiation. Water, Air, and Soil Pollution, 228(9). https://doi.org/10.1007/s11270-017-3557-4
Morales-Flores, N., Pal, U., & Sánchez Mora, E. (2011). Photocatalytic behavior of ZnO and Pt-incorporated ZnO nanoparticles in phenol degradation. Applied Catalysis A: General, 394(1–2), 269–275. https://doi.org/10.1016/j.apcata.2011.01.011
Ng, K. H., & Cheng, C. K. (2015). A novel photomineralization of POME over UV-responsive TiO2 photocatalyst: kinetics of POME degradation and gaseous product formations. RSC Advances, 5(65), 53100–53110. https://doi.org/10.1039/c5ra06922j
Ng, K. H., & Cheng, C. K. (2016). Photo-polishing of POME into CH4-lean biogas over the UV-responsive ZnO photocatalyst. Chemical Engineering Journal, 300, 127–138. https://doi.org/10.1016/j.cej.2016.04.105
Ng, K. H., Deraman, M. R., Ang, C. H., Chong, S. K., Kong, Z. Y., Khan, M. R., & Cheng, C. K. (2014). Phototreatment of palm oil mill effluent (POME) over Cu/TiO2 photocatalyst. Bulletin of Chemical Reaction Engineering and Catalysis, 9(2), 121–127. https://doi.org/10.9767/bcrec.9.2.6011.121-127
Ng, K. H., Khan, M. R., Ng, Y. H., Hossain, S. S., & Cheng, C. K. (2017). Restoration of liquid effluent from oil palm agroindustry in Malaysia using UV/TiO2 and UV/ZnO photocatalytic systems: A comparative study. Journal of Environmental Management, 196, 674–680. https://doi.org/10.1016/j.jenvman.2017.03.078
Rajani, A., Kusnadi, Santosa, A., Saepudin, A., Gobikrishnan, S., & Andriani, D. (2019). Review on biogas from palm oil mill effluent (POME): Challenges and opportunities in Indonesia. IOP Conference Series: Earth and Environmental Science, 293(1). https://doi.org/10.1088/1755-1315/293/1/012004
Saputera, W. H., Amri, A. F., Daiyan, R., & Sasongko, D. (2021). Photocatalytic technology for palm oil mill effluent (POME) wastewater treatment: Current progress and future perspective. Materials (Vol. 14, Nomor 11). MDPI AG. https://doi.org/10.3390/ma14112846
Saputera, W. H., Amri, A. F., Mukti, R. R., Suendo, V., Devianto, H., & Sasongko, D. (2021). Photocatalytic degradation of palm oil mill effluent (Pome) waste using BiVO4 based catalysts. Molecules, 26(20). https://doi.org/10.3390/molecules26206225
Turkyilmaz, S. S., Guy, N., & Ozacar, M. (2017). Photocatalytic efficiencies of Ni, Mn, Fe and Ag doped ZnO nanostructures synthesized by hydrothermal method: The synergistic/antagonistic effect between ZnO and metals. Journal of Photochemistry and Photobiology A: Chemistry, 341, 39–50. https://doi.org/10.1016/j.jphotochem.2017.03.027
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